
Personal Protective
Equipment

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| Objectives: By the end of this section,
participants will be able to select, don, doff and store appropriate personal protective
equipment. Why this section is
important: Once you have identified the hazards and minimized the ambient concentrations
of toxins, personal protective equipment may be necessary to make the workplace safe for
entry. |
Goals of Personal Protective
Equipment
Level A Protection
Level B Protection
Level C Protection
Level D Protection
Chemical Protective Clothing
Sources of Contamination
Chemical Protective Equipment
Inspection
Frequency of Inspection
Suit Leak Test Methods
Chemical Protective Equipment Storage
Goals
of Personal Protective Equipment |
- Shield or isolate individuals from the chemical, physical,
and biologic hazards that may be encountered on-site
- Prevent injury to the wearer from incorrect use and/or
malfunction of the personal protective equipment (PPE)
Note: Personal Protective Equipment is to
be used only after engineering controls and administrative controls are unable to lower
the ambient concentrations below acceptable levels. |
Level A Protection

|
Required
when the greatest potential for exposure to hazards exists, and when the greatest level of
skin, respiratory, and eye protection is required. Note the totally encapsulating
(air-tight) suit. |
Typical Level A Equipment:
Positive pressure, full face-piece self-contained
breathing apparatus (SCBA) or positive pressure supplied air respirator with escape SCBA
- Totally-encapsulating chemical-protective suit

- Inner and/or outer chemical-resistant gloves
- Disposable protective suit, gloves and steel-toe boots
|
Warranted Level A Conditions
- Hazardous substances have been identified and require the
highest level of protection for skin, eyes, and the respiratory system
- The atmosphere contains < 19.5 % oxygen
- Site operations involve a high potential for splash,
immersion, or exposure to unexpected materials that are harmful to the skin
- Operations are being conducted in confined, poorly
ventilated areas, and the absence of hazardous substances has not yet been determined
- Direct-reading instruments indicate high levels of
unidentified vapors or gases in the air
|
Level B Protection

|
| Required under
circumstances requiring the highest level of respiratory protection, with a lesser level
for skin protection. Note the non-totally-encapsulating suit. |
Typical Level B Equipment:
Positive pressures, full face-piece SCBA or positive
pressure supplied air respirator with escape SCBA
- Inner and/or outer chemical-resistant gloves
- Hooded chemical resistant clothing
- Outer chemical-resistant boots
|
Warranted Level B Conditions
- The type and atmospheric concentration of substances have
been identified and require a high level of respiratory protection, but less skin
protection than Level A
- The atmospheric contains < 19.5 % oxygen
- The presence of incompletely identified vapors and gases is
indicated but they are not suspected of being harmful to the skin
|
Level C Protection |
| Employed when
the concentration and type of airborne substances is known, and the criteria for using air
purifying respirators is met. |
Typical Level C Equipment
- Full-face air-purifying respirators

- Inner and outer chemical-resistant gloves
- Chemical-resistant clothing
- Disposable chemical-resistant outer boots
|
Warranted Level C Conditions
- The atmospheric contaminants, liquid splashes or other
direct contact will not adversely affect or be absorbed by the skin
- The types of air contaminants have been identified and air
purifying respirators can lower breathing zone concentrations to acceptable levels
- Oxygen concentrations are not < 19.5 % by volume
|
Level D Protection |
Required when the least potential for exposure to hazards exists, and when the
least level of skin, respiratory, and eye protection is required. |
Typical Level D Equipment
- Chemical-resistant steel-toe boots or shoes
|
Warranted Level D Conditions
- No contaminants are present
- Work operations preclude splashes, immersion, or the
potential for unexpected inhalation of or contact with hazardous level of any chemicals
|
Chemical Protective Clothing |
| Non-elastomers
(non-elastic, non-stretchable)
|
Elastomers (elastic,
stretchable)
Polyethylene
- Chlorinated Polyethylene (CPE) or Chloropel
|
Sources of Contamination |
- Permeation: The diffusion of gases through a material.
Measured in permeation rates (ug/cm2/min) or breakthrough time (in minutes).
Breakthrough time is the time necessary for a chemical to permeate a protective
barrier, such as a chemical protective suit.
- Penetration: The flow of liquids, gases, or vapors through
pinholes, zippers, sticked seams, other imperfections, or the material.
- Degradation: Physical changes in a material from chemical
exposure, wear and tear, and chemical decomposition.
|
Chemical Protective Equipment
Inspection |
- Determine that the clothing material is correct for the
specified task
- Visually inspect for imperfect seams, non-uniform coatings,
tears, malfunctioning closures
- Hold up to light and check for pinholes.
- Flex product and observe for cracks, observe for other signs
of shelf deterioration. If the product has been used previously, inspect inside and out
for signs of chemical attack for discoloration, swelling or stiffness.
|
Suit Leak Test Methods |
- Light Test - In a dark room, shine a light on the suit and
look for light penetration.
- Carbon Monoxide Test - Place a carbon monoxide sensor in the
suit, seal it and place in a room with a high concentration of carbon monoxide.
- Shower Test - Wear the suit and look for penetration.
Note: It is difficult to distinguish between penetration and perspiration so the
reliability of this test is questionable.
- Soapsuds Test - Pressurize the suit and spray soapy water on
the suit while looking for telltale bubbles.
- Pressure Retention Test - Pressurize the suit and monitor
the pressure over time. Compare to manufacturer's specifications.
|
Chemical Protective Equipment Storage |
- Store separate from street clothing
- Segregate Personal Protective Equipment by type and material
- Always store according to the manufacturers directions.
|
Thought
Questions (you do not need to respond): |
| Is it desirable to always use
the highest level of personal protective equipment (i.e., Level A) under all
circumstances? What would be potential drawbacks? |

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